mer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ3 S,N 1,O)(methanol-κO)(1,10-phenanthroline-κ2 N,N′)nickel(II)
نویسندگان
چکیده
In the title compound, [Ni(C(8)H(5)Cl(2)N(3)OS)(C(12)H(8)N(2))(CH(3)OH)], the Ni(II) atom is octa-hedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thio-semicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. The crystal structure is constructed by N-H⋯Cl, N-H⋯N, C-H⋯S and O-H⋯S hydrogen bonds.
منابع مشابه
(4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ3 O 2,N 1,S)(1,10-phenanthroline-κ2 N,N′)zinc(II) dimethyl sulfoxide disolvate monohydrate
The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(12)H(8)N(2))]·2C(2)H(6)OS·H(2)O, is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment. Hydrogen bonds link the mononuclear mol-ecule, the water and the dimethyl sulfoxide (DMSO) mol-ecules into a linear chain motif. One DMSO mol-ecule is disordered over ...
متن کاملDichlorido[N′-(3,5-dichloro-2-hydroxybenzylidene)pyridine-4-carbohydrazide-κN](1,10-phenanthroline-κ2 N,N′)cobalt(II) methanol monosolvate
In the title compound, [CoCl(2)(C(13)H(9)Cl(2)N(3)O(2))(2)(C(12)H(8)N(2))]·CH(3)OH, the Co(II) atom is octahedrally coordinated by two N atoms from the pyridyl rings of the tridentate N'-(3,5-dichloro-2-hydroxy-benzyl-idene)pyridine-4-carbohydrazide (H(2)L) ligand, two N atoms from the 1,10-phenanthroline ligand and two chloride ions. The acyl-hydrazone groups are not involved into the coordina...
متن کاملDi-μ-benzoato-κ3 O,O′:O;κ3 O:O,O′-bis[aqua(nitrato-κO)(1,10-phenanthroline-κ2 N,N′)lead(II)]
The title compound, [Pb(2)(C(7)H(5)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], crystallizes as a dinuclear centrosymmetric dimer containing two Pb(II) atoms bridged by two benzoate ligands. Each Pb(II) atom is seven-coordinated by a water mol-ecule, a nitrate anion, a 1,10-phenanthroline (phen) ligand and two benzoate anions. The crystal packing is stabilized by O-H⋯O hydrogen bonds and by...
متن کاملmer-Triaqua(1,10-phenanthroline-κ2 N,N′)(sulfato-κO)magnesium(II)
In the title compound, [Mg(SO(4))(C(12)H(8)N(2))(H(2)O)(3)], the Mg(II) centre exhibits a slightly distorted octa-hedral coordination environment defined by two N atoms from a 1,10-phenanthroline mol-ecule, one O atom from a sulfate dianion and three meridionally arranged O atoms from coordinated water mol-ecules. The crystal structure involves intra- and intermolecular O-H⋯O hydrogen bonds.
متن کاملAqua(9,10-dioxoanthracene-1,5-disulfonato-κO 1)bis(1,10-phenanthroline-κ2 N,N′)nickel(II)
In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octa-hedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water mol-ecule. An intra-molecular O-H⋯O hydrogen bond occurs. In the crystal, inter-mo...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009